It was narrated that Anas bin Malik said:
The Messenger of Allah (ﷺ) used to pray Zuhr when the sun passed its zenith, and he would pray 'Asr between these two prayers; and he would pray Maghrib when the sun had set, and he used to pray 'Isha' when the twilight had disappeared, then he said straight after that: And he would pray Fajr when a man could see clearly.